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India to soon be the hub for production and export of Hydrogen: Shri Hardeep Singh Puri

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Union Minister Hardeep S Puri flags-off 1st Green Hydrogen Fuel Cell Bus from Kartavya Path, New Delhi


With Hydrogen, India’s foray into Clean & Green Energy is nothing less than revolutionary: Shri Hardeep Singh Puri

India to soon be the hub for production and export of Hydrogen: Shri Hardeep Singh Puri

Posted On: 25 SEP 2023 4:35PM by PIB Delhi

Reiterating Prime Minister’s vision that not only will green hydrogen be the basis of green growth through green jobs but it will also set an example for the world towards clean energy transition, “Addressing the nation from the ramparts of the historic Red Fort in Delhi, Hon’ble Prime Minister announced self-reliance in energy production through a mix of electric mobility, gas-based economy and taking Green Hydrogen on Mission mode,” said Union Minister of Petroleum & Natural Gas and Housing & Urban Affairs Shri Hardeep Singh Puri, addressing on the occasion of flagging-off 1st Green Hydrogen Fuel Cell Bus from Kartavya Path, New Delhi. Shri Rameswar Teli, Minister of State for Petroleum and Natural Gas & Labour and Employment; Shri Pankaj Jain, Secretary, MoP&NG, Shri S M Vaidya, Chairman, IndianOil were also present on the occasion.

Flagging-off the first Hydrogen cell bus in presence of young school children, officials and media persons, Shri Hardeep Singh Puri explained the concept of Hydrogen and the benefits of using it as the fuel for future, “The fuel cell utilizes Hydrogen and air to generate electricity to power the bus and the only by-product from the bus is water therefore making it possibly the most environmentally friendly mode of transportation as compared to conventional buses that run on diesel and petrol. With three times the energy density and the absence of harmful emissions, hydrogen shines as a cleaner, more efficient choice to meet the energy requirements.” Additionally, the buses powered with hydrogen cells takes few minutes to fully charge itself, added Shri Puri.

 

Speaking about the Government’s ambitious plans on clean and green energy, Shri Hardeep Singh Puri said that emerging fuels like hydrogen and bio-fuels shall account for 25% of global incremental energy demand growth over the next two decades. “With one of the largest synchronous grids in the world, we have achieved ‘One Nation-One Grid-One Frequency’, and would soon be global champion in production and exports of Hydrogen and is set to emerge as the Hub for green hydrogen”, he added.

Complimenting Industry and Government’s collaboration in taking India on a global platform and ensuring that it becomes a global hub for cleaner technologies and achieving self-reliance in energy soon, “We were privy to the launch of the world’s first BS 6 (Stage II) Electrified Flex Fuel vehicle prototype that encompasses both the flex fuel engine as well as an electric powertrain that offers higher use of ethanol combined with better fuel efficiencies. Now with flagging-off the first two hydrogen cell buses, we have set the ball rolling and expect another 15 such buses to ply on Delhi NCR roads by the end of this year”, stated the Petroleum Minister.

Marking the green hydrogen powered buses as a game changer for the city transport in the Country, Shri Hardeep Singh Puri complimented IndianOil for undertaking this collaborative approach along with Tata Motors for development of indigenous solutions pertaining to Fuel Cell and hydrogen infrastructure in the country. “Success of this project can catapult India from being net importer of fossil energy to becoming net exporter of clean hydrogen energy”, added Shri Puri.

Speaking on the occasion, Shri Rameshwar Teli said, “The Green Hydrogen Mission which aims to establish a Green Hydrogen ecosystem in India, is on a developmental and progressive path. Hydrogen will be a key player in the transition to a carbon-free economy and will help mitigate climate change. Today’s launch will certainly revolutionize India’s firm commitment of being a cleaner and greener nation.”

Addressing the gathering Shri Pankaj Jain, Secretary, MoP&NG said that we are at a crucial inflection point of technology and mobility. “Today's flag off of Green Hydrogen bus is a symbol of how mobility will transform and how India will move away from conventional fuels. My compliments to IndianOil for this revolutionary foray in hydrogen”. He also encouraged school children to be inquisitive about new green technologies and learn about how these technologies will move us away from internal combustion engines.

Earlier in the day, welcoming the dignitaries, Shri S M Vaidya, Chairman, IndianOil said that Hydrogen, is poised to be game changer in India's ambitious quest to achieve Net-Zero emissions by the year 2070. “In-line with Hon’ble Prime Minister’s vision for National Green Hydrogen Mission, today’s flag-off of green hydrogen fuel cell buses is a testament to IndianOil's steadfast commitment towards devising sustainable solutions for greening the Mobility sector. With the active support from Govt. of India and Ministry of Petroleum & Natural Gas, this milestone marks a pivotal stride in nation’s journey towards zero emission mobility.   Under this program, 15 fuel cell buses will be plying on specified routes in the Delhi NCR Region to establish the performance data under Indian operating conditions. These 15 buses shall cover a cumulative 3 lakh kilometres to establish the efficacy, efficiency and sustainability of the complete value chain.”



Shri Nitin Gadkari calls upon all stakeholders to come forward and support the Vehicle Scrapping policy describing it is a win-win situation for all

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Shri Nitin Gadkari calls upon all stakeholders to come forward and support the Vehicle Scrapping policy describing it is a win-win situation for all

Posted On: 25 SEP 2023 5:41PM by PIB Delhi

Union Minister for Road Transport and Highways Shri Nitin Gadkari called upon all stakeholders to come forward and support the Vehicle Scrapping policy. Addressing a Stakeholder Consultation in New Delhi today he said it is a win-win situation for all.The Union Minister said the Ministry has undertaken multiple initiatives to build resilient demand for vehicles such as building a world-class network of Highways, Electrification of buses, and mandatory automated fitness testing of vehicles. He said the Auto OEMs should work towards increasing their production capacity and support the nation to become the largest auto industry in the world.

Shri Gadkari emphasized that since the Auto industry is the biggest beneficiary of this policy, they must come forward and support on 3 main pillars of more investment in setting up Automated Testing Stations (ATSs) and Registered Vehicle Scrapping Facilities (RVSFs), more awareness amongst citizens about the policy benefits through their dealer network and a finalized discount % against certificate of deposit obtained by citizens on scrapping vehicles.

Secretary Shri Anurag Jain encouraged the auto industry to set up scrap centers and automated testing stations across the country. It was emphasized that Vehicle Scrapping Policy is expected to increase auto sales by about 8% and contribute about 0.5% to the country’s GDP and hence, Auto OEMs must extend unconstrained support to the policy.

This stakeholder consultation aimed to seek support from the automobile industry to expedite the implementation of vehicle scrapping policy in the form of investment in vehicle scrapping infrastructure of Registered Vehicle Scrapping Facilities (RVSFs) and Automated Testing Stations (ATSs), generation of awareness among citizens and extension of discounts to vehicle owners for scrapping vehicles at RVSFs. Representatives from all major automotive OEMs (including Tata, Mahindra, Maruti, Kia, Hyundai, etc.), auto dealers and used car aggregators (including Car Dekho, Cars24) attended the event and shared their perspectives on the challenges and actions required to expedite implementation of the vehicle scrapping policy.

Additional Secretary Shri Mahmood Ahmed welcomed the dignitaries and industry participants and highlighted key benefits of V-VMP. This was followed by a presentation on status of V-VMP and support required from auto industry by Director Shri Paresh Goel.

SIAM also presented their views on the incentives for citizens through this policy and good inputs were provided by all other auto industry stakeholders.

The Ministry of Road Transport and Highways (MoRTH) launched the Voluntary Vehicle-Fleet Modernization Program (Vehicle Scrapping Policy) in 2021. This Policy is aimed at creating an ecosystem for phasing out old, unsafe, polluting vehicles and replacing them with newer, safer, and fuel-efficient vehicles.

PROMOTIONAL WORK BY FERTILISER INDUSTRY

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Maintenance Practices and Case Studies

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Environmental Legislation Concerning Fertiliser Industry

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ENERGY & ENVIRONMENT

Environmental Legislation Concerning Fertiliser Industry

Although provisions for environmental regulation and legal action have existed in India for some time in the form of the Factories Act and the Indian Forests Act, rapid industrialization and urbanization found these Acts to be inadequate.  It was, therefore, necessary to have a uniform national law covering broad environmental problems endangering the health and safety of people as well as the protection of flora and fauna.  Consequently, India, which participated in the 1972 United Nations’ Stockholm Conference on Human Environment, decided to implement the decisions of the Conference related to pollution, preservation, and protection of the environment. 

Pollution control to preserve the environment is universally practiced mainly through the development of environmental protection standards, their implementation, and taking legal action against violators.  The environmental protection standards are essential to ensure that the pollutants discharged from the industry into the environment are within the capacity of the environment to assimilate them through natural purification processes. 

In India, the first organization that attended to the need for developing and promoting standards for environmental protection was the Bureau of Indian Standards (BIS).  The BIS laid down environmental protection (EP) standards even before any legislation in this regard was conceived.  However, the BIS standards are only recommendations and are not legally binding. 

The first legislation came into existence in 1974 specifically to protect the water component of the environment.  This legislation, referred to as the Water (Pollution Prevention and Control) Act, was followed in 1981 by the Air (Pollution Prevention and Control) Act.  The Environment (Protection) Act of 1986, an umbrella Act covers all facets of the environment, which the Public Liability Insurance Act of 1991 has been designed to provide immediate relief to the person(s) affected by accidents occurring while handling hazardous substances.  A discussion of these Acts follows.



Fertilizer Policy in India - Constitutional Provisions, Challenges, Important Terms & More

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 The Fertilizer Policy in India plays a significant role in the Indian Economy. Since the inception of the New Economic Policy in 1991, many attempts have been made to reform the fertilizer sector in India. The issue of agricultural subsidies in India should be viewed in the context of the country’s overall economic condition, the importance of farmers and the agricultural industry to the country’s political economy, and current trends in the country’s agricultural economy.

Fertilizer Policy in India is one of the important topics for the UPSC IAS exam. It covers a significant part of the UPSC Mains General Studies Paper 3 Syllabus and General Studies 2 Paper.

Recent Update

A new DAP Subsidy has been approved by the government of India for the year 2022 (Kharif season). The price of DAP has increased from Rs 1,200 a bag to almost Rs 1,350 per 50 kg bag, which denotes an increase of 12.5 per cent.

Fertilizer Policy in India

India is the second biggest consumer of fertilizer in the world, next only to China. The fertilizer industry is essential to the Indian Economy because agriculture is a crucial sector. India’s fertilizer business is extremely important since it produces some of the most important raw ingredients for agricultural production.

  • The main goal of fertilizer sector is to guarantee the entry of primary and secondary elements in the quantities required for agricultural production.
  • In India, the fertilizer business is largely responsible for the agricultural sector’s success. India’s food business has become a global leader in this sector largely due to the number of technically skilled fertilizer manufacturers there.
  • During the projected period, the Indian fertilizers market is anticipated to increase at a compound yearly growth rate of 11.9 percent (2021-2026).
  • In 2020, the Indian fertilizer market had a worth of INR 887 billion. The rise has significantly aided the country’s sustainable production of food grains in fertilizer consumption.
  • Numerous world-class government and private fertilizer firms are based in India. The numerous fertilizer firms in India, which produce everything from seeds to fungicides, are the main factor in the sector’s development in India.

City Compost Policy

City Compost Policy involves the process and uses city waste as compost. This policy was approved in 2016. Under the policy, the assistance of Rs 1,500 per tonne of city compost was to be provided to fertilizer companies for marketing and promotion of city compost. The Ministry of Chemicals and Fertilizers introduced it. In 2021 the policy on the promotion of city compost was discontinued.

Phosphatic and Potassic (P&K) Policy

nutrient Based Subsidy Scheme was announced in 2009 for Phosphatic & Potassic fertilizers to ensure the Nation’s food security, improve agricultural productivity, and ensure the balanced application of fertilizers. According to the NBS Policy, the government annually announces a fixed rate of subsidy (in Rs per Kg) for the nutrients nitrogen (N), phosphate (P), potassium (K), and Asulphur (S). basis. The per Kg subsidy rates on the nutrients N, P, K, and S are converted into per Tonne subsidy on the various P&K fertilizers covered under NBS Policy.

Urea Policy (Pricing and Administration)

Under urea policy, there are 32 urea units in the country, of which 31 urea units use Natural Gas (domestic gas/LNG/CBM), and the remaining urea unit uses Gas & Naphtha as feedstock. 

Fertilizer Subsidy in India

The subsidy offered to farmers for using fertilizers is known as a fertilizer subsidy. Farmers purchase fertilizers at MRPs (Maximum Retail Prices), less expensive than the market rates determined by supply and demand or the cost of production or importation. The farmer, who pays MRPs less than the market-determined rates, is the true subsidy recipient, even though fertilizer businesses receive it. Until recently, businesses earned payment only after their bagged goods were sent and retrieved at a district’s railhead point or authorized godown.

Direct Benefit Transfer

  • A new Direct Benefit Transfer (DBT) system, which went into effect in March 2018, requires that corporations only receive subsidies after making actual sales to farmers.
  • Over 2.3 lakh retailers operate in India, each with a Point of Sale (PoS) system connected to the Department of Fertilizers’ e-Urvarak DBT portal.
  • Anyone purchasing fertilizers on a subsidized basis must provide their Kisan Credit Card number or unique Aadhaar identity.
  • The PoS device must record the quantities of the fertilizers purchased, the buyer’s identity, and biometric authentication.
  • A company can only apply for a subsidy after registering the sale on the e-Urvarak platform; payments are processed weekly and sent electronically to the company’s bank account.
  • Recent Fertilizer Policy in India

    The fertilizer Policy in India is significant for Indian culture, and since India’s independence, the government has regulated fertilizer sales, prices, and quality. The Indian government has introduced several Fertilizer Policies to regulate the sector.

    New Pricing Scheme

    The Concession Scheme for urea units in India is based on the feedstock prices and the plants' age. This scheme has been implemented in various phases, such as NPS-I (2003-2004), NPS-II (2004-2006), and NPS-III (2006 onwards). Under this scheme, the difference between the cost of production and the selling price or Maximum Retail Price (MRP) is provided as a subsidy or concession to the manufacturers. Urea is the only fertilizer subject to price control, and it is sold at a specified uniform sale price determined by the government. On the other hand, Phosphatic and Potassic fertilizers are not subject to price control and are sold at indicative maximum retail prices (MRPs).

    Objective

    The objective is to assist urea units in attaining internationally competitive efficiency levels. This entails promoting transparency and simplifying the administration of subsidies.

    Effects

    The policy of fixed urea prices in India resulted in market distortions. Fertilizer companies faced financial difficulties due to the fixed prices, while the costs of inputs like natural gas and naptha continued to rise. Since a significant portion (80%) of urea production in India relies on gas-based methods, this further exacerbated the issue. Another consequence of this policy was an imbalance in the utilization of fertilizers. Some sectors may have misused the availability of subsidized urea, leading to illegal exports and the improper use of urea in activities like the preparation of adulterated milk.

    Also, check out the article on Important Government Schemes in detail here!

    Nutrient Based Subsidy (NBS) Policy, 2010

    • Nutrient Based Subsidy (NBS) Programme for Fertilizers was initiated by the Ministry of Chemicals & Fertilizers’ Department of Fertilizers in April 2010.
    • With the exception of urea, each grade of subsidized phosphoric and potassium (P&K) fertilizers receives a fixed level of subsidy under NBS based on the number of nutrients they contain.
    • It is primarily done for secondary nutrients like N, P, K, and S, which are crucial for crop growth and development.
    • Since the retail pricing of these non-urea fertilizers is deregulated and set by manufacturers, it attempts to ensure they are accessible to farmers at a reasonable cost.

    Neem Coated Urea Policy, 2015

    Domestic fertilizer companies are legally required to “Neem coat” at least 75% of their urea production, which can even go up to 100 percent. There used to be a 35 percent cap on this. Additionally, the government has permitted businesses to increase the price of urea coated with neem by just 5%.

    Objective

    The objective is to ensure sustainable agriculture, preserve soil health, and optimize crop yields while reducing reliance on imported urea and minimizing environmental impact.

    Advantages

    Reduction in the subsidy. As a result, rationalizing the subsidy burden on the Government of India. Prevention of diversion of urea for industrial use

    Limitations

    The amount of subsidy savings resulting from these efforts is relatively small compared to the significant financial and political magnitude of the fertilizer subsidy paid on the three major fertilizers - nitrogen (N), phosphorus (P), and potassium (K).

    Gas Pooling Policy, 2015

    The ‘Gas price pooling’ mechanism was introduced on 1 July 2015 in place in India. This policy creates a standard rate for fertilizer plants by averaging or pooling the costs of domestic and imported LNG. Natural gas is the same price for all fertilizer factories across the nation as the raw material used to create urea. By setting gas prices at the same level for all participants, the Gas Price Pooling aims to alter the dynamics of the urea industry. In the past, every plant had to develop its agreements or contracts on unique costs with various suppliers.

    New Urea Policy, 2015

    The New Urea Policy was introduced in May 2015. The Policy aims to boost domestic urea output, encourage urea production that uses less energy, and lighten the central government’s subsidy load. The purpose of this policy is to encourage domestic producers and provide free shipping of phosphorus and potassium fertilizers.

  • Role of Fertilizer Association of India (FAI)

    The Fertiliser Association of India (FAI) is a non-profit and non-trading company that represents majorly the fertilizer manufacturers, distributors, importers, and equipment. Fertilizer Association of India was established in 1955 to bring together everyone involved in fertilizer manufacturing, marketing, and consumption with the goal of :

    • Assisting the industry in improving its operative efficiency
    •  Finding solutions to the problems facing the fertilizer industry and agriculture
    • Encourage the wise and effective use of fertiliser.
    • Promote the consumption of more nutritious plant foods.
    • Encourage research and conversation about all issues that affect good agriculture practices.
    • Ensuring Food Security through the balanced and efficient use of plant nutrients is the prime objective of the Association.



India is committed to achieve the Net Zero emissions target by 2070 as announced by PM Modi, says Dr. Jitendra Singh

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 Ministry of Science & Technology

azadi ka amrit mahotsavg20-india-2023

India is committed to achieve the Net Zero emissions target by 2070 as announced by PM Modi, says Dr. Jitendra Singh


“India has remained steadfast in its transition towards clean energy achieving the fastest pace of renewable capacity addition amongst all major economies and ambitious transition goals articulated by Prime Minister Modi, in India’s Panchamrit declaration at COP26”: Dr Jitendra Singh

India’s energy-mix strategies include a larger shift toward clean energy alternatives, increased manufacturing capacities, energy use efficiency and a policy push for Hydrogen including production-linked incentives, says Dr Jitendra Singh

Posted On: 28 SEP 2023 6:38PM by PIB Delhi

Union Minister of State (Independent Charge) Science & Technology; MoS PMO, Personnel, Public Grievances, Pensions, Space and Atomic Energy, Dr. Jitendra Singh, has said India is committed  to achieve the Net Zero emission target by 2070, as announced by Prime Minister Shri Narendra Modi.

“We are fully committed to contribute in attaining the United Nations Sustainable Development Goals (SDGs) -  by way of Research and Innovation through international collaboration and partnerships,” he said, participating in the ‘Green Ribbon Champions’ programme in New Delhi today.

Dr Jitendra Singh said, India is set to achieve its short term and long term targets under the Panchamrit action plan, like- reaching a non-fossil fuel energy capacity of 500 GW by 2030; fulfilling at least half of its energy requirements via renewable energy by 2030; reducing CO2 emissions by 1 billion tons by 2030; reducing carbon intensity below 45 percent by 2030; and finally pave the way for achieving a Net-Zero emission target by 2070.

Dr Jitendra Singh said, PM Modi had at the 26th session of the Conference of the Parties (COP26) to the United Nations Framework Convention on Climate Change (UNFCCC) held in Glasgow, United Kingdom in November, 2021, expressed to intensify India’s Climate Action Plan (CAP) by presenting to the world five nectar elements (Panchamrit) of India’s climate action plan. He said, apart from a five-pronged target for India and its commitment to Net-Zero emissions by 2070, PM Modi also asserted the need to follow a sustainable lifestyle and emphasised on the idea of making ‘Lifestyle for Environment’ (LiFE) a global mission through bolder steps by the global clean energy fraternity.

Dr Jitendra Singh said, the Mission Innovation (MI) and International Solar Alliance, spearheaded by PM Modi, were announced at COP21 in 2015, when the United Nations conferred on him the ‘Champions of Earth Award 2018.’

The term ‘Mission Innovation’ was coined by PM Modi. Mission Innovation (MI) is a global initiative of 23 countries and the European Commission (on behalf of the European Union) to accelerate the Clean Energy revolution and progress towards the Paris Agreement goals and pathways to net zero. India is a founding member of Mission Innovation.

The first phase of Mission Innovation (MI) (2015-2020) was announced at COP21 on November 30, 2015. In the first phase of Mission Innovation, India led three MI Innovation Challenges, such as Smart Grids, Off Grid Access to Electricity and Sustainable Biofuels, and hosted many workshops. 

Dr Jitendra Singh said, Government of India through Public-Private Partnerships is ensuring the funding for clean energy innovations as envisioned under Mission Innovation 2.0. He said that the Clean Energy Ministerial (CEM) setup has been able to provide a unique opportunity for India to showcase its contribution to clean energy development nationally & internationally and quoted some major CEM initiatives which includes CEM’s Global Lighting Challenge (GLC) campaign, Street Lighting National Programme, Unnat Jyoti by Affordable LEDs for All (UJALA) programme and the ‘One Sun-One World-One Grid’ Initiative which was first floated by the Prime Minister to harness tremendous potential of solar energy.

Referring to the G20 Summit earlier this month, Dr Jitendra Singh said the New Delhi Declaration committed itself to implement India’s initiative of 'Lifestyle for Environment Mission’ (LiFE) and promote Artificial Intelligence towards achieving the UN SDGs. By adopting the 'Green Development Pact,' G-20 has also reaffirmed its commitments to sustainable and green growth.

The Union Minister said that the Global Biofuels Alliance (GBA) to be led by India, Brazil and the United States, as leading biofuel producers and consumers, will greatly help achieve the MDG Goals of India turning Net Zero by 2070.

“GBA is a landmark achievement agreed to by the leaders of Singapore, Bangladesh, Italy, USA, Brazil, Argentina, Mauritius and UAE, at the initiative of PM Modi on the sidelines of the G20 Summit. GBA aims to serve as a catalytic platform, fostering global collaboration for the advancement and widespread adoption of biofuels,” he said.

Dr Jitendra Singh said India stands at the forefront of addressing the global challenge of Climate Change and has committed to an ambitious Nationally Determined Contributions (NDCs) of reducing emission intensity by 33-35% in 2030 against the levels of year 2005.

“India has remained steadfast in its transition towards clean energy, achieving the fastest pace of renewable capacity addition amongst all major economies and ambitious transition goals articulated by Prime Minister Modi, in India’s Panchamrit declaration at COP26,” he said.

The Union Minister said that the last nine years have witnessed the Indian crusade against climate change. “We have already achieved our commitment of 40% energy production from renewable sources, way ahead of the 2030 Paris Agreement target,” he said.

The Minister reiterated India is implementing the largest Renewable Energy (RE) expansion program in the world, envisaging a 5-fold increase in the overall RE capacity.

He added that apart from the thrust on renewable energy from solar and hydel, the Prime Minister announced major strides in Hydrogen energy in his Independence Day Address from the ramparts of the Red Fort on 15th August 2021. India also launched the National Hydrogen Energy Mission to enable cost competitive green hydrogen production.

“India’s energy-mix strategies include a larger shift toward clean energy alternatives, increased manufacturing capacities, energy use efficiency and a policy push for Hydrogen including production-linked incentives. In addition, the emerging technologies like 2G Ethanol Pilot, Comfort climate box for tropical regions, Hydrogen Valleys, Heating and cooling virtual repository, are all on the table,” he said.

Dr Jitendra Singh said India has developed a roadmap and a strategy for a Bio-based economy which is inching towards 150 billion USD by the year 2025. Department of Biotechnology has been supporting R&D innovations in Advanced Biofuels and ‘Waste to Energy’ technologies. India has established 5 Bioenergy Centers with an interdisciplinary team working on advanced sustainable biofuels using modern biotechnology tools.

“This will facilitate infrastructure for Bio-manufacturing of low-carbon bio-based products. Sustainable biofuels play a key role in reducing Green House Gas (GHG) emissions from the transport sector,” he said.

Dr Jitendra Singh said, India is among the few countries in the world to design a Cooling Action Plan (CAP) with a long-term vision (spanning a 20-year period from 2017-18 to 2037-38) that addresses cooling requirements across sectors.

“CAP identifies possible actions to reduce cooling demand arising from residential and commercial buildings, cold chains, etc., covering aspects of building design and technological innovations that do not compromise on energy efficiency,” he said.

Recalling that he launched India’s first truly indigenously developed Hydrogen Fuel Cell Bus developed by KPIT-CSIR in Pune on 21 Aug 2022, Dr Jitendra Singh said the painstaking efforts undertaken over the last two years since the Prime Minister had announced India’s intention to create a dedicated mission for Green Hydrogen, culminated in the announcement of the National Green Hydrogen Mission with a budgetary outlay of about 2.4 billion dollars in January this year.

He said that a draft R&D Roadmap for Green Hydrogen Ecosystem in India has been released. A PPP framework for R&D called the Strategic Hydrogen Innovation Partnership or SHIP will be facilitated under the Mission. 

“India is uniquely poised to emerge as a prominent global leader in production of Green Hydrogen not just on the basis of its abundant renewable energy resources and the benefits of one of the world’s lowest costs of regeneration, but also because of its R&D ecosystem and the framework designed for R&D in cross-cutting sectors of hydrogen production, transport, electrolyze manufacturing, support infrastructure, fuel cell EVs, storage and utilization,” he said.

Dr Jitendra Singh further said that nearly 9% share of electricity is likely to be contributed from India’s nuclear sources by the year 2047. The Department of Atomic Energy aims to achieve 20 GW capacity of nuclear power generation by the year 2030 which will be a major milestone placing India as the third largest producer of atomic energy in the world after the USA and France.

“Credit for this rapid stride goes to Prime Minister Narendra Modi, who for the first time after Independence took the decision of approving 10 reactors in fleet mode in a single order and allowed nuclear installations to be developed under joint ventures with PSUs. As a result, today India is sixth largest in the world in the number of reactors that are functional and second largest in the total number of reactors including those under construction,” he said.

Dr Jitendra Singh mentioned sustainable practices in fisheries, marine research, coastal tourism and renewable energy generation. He said, by harnessing the potential of the Blue Economy, we can ensure the well-being of our oceans while driving economic development in a sustainable and responsible manner. We are also concerned about increased plastics and microplastics in our oceans, another important area to focus as it enters into our food chain as several marine organisms consume them.

Dr Jitendra Singh said, the National Research Foundation (NRF) Bill, 2023, passed by the Parliament in the last monsoon session, will promote the culture of research and innovation throughout India’s universities, colleges, research institutions, and R&D laboratories at a total estimated cost of Rs. 50,000 crores during five years and this will give further impetus to Clean energy research in India and Mission Innovation. As much as 70% of its funding will come from non-governmental sources, he said.

Dr Jitendra Singh said, despite efforts by countries to check and reduce emission of greenhouse gases, the global average temperature in 2100 is expected to rise to around 2.1°C above pre-industrial levels. The Minister pointed out that this falls short of the goals stipulated in the Paris Agreement, which calls for limiting the global temperature to 1.5°C above pre-industrial-era levels by the end of the century.

Dr Jitendra Singh said, Precision irrigation, Innovative clean water technologies, such as water purification systems, desalination techniques, and wastewater treatment technologies are to be further augmented and implemented. 


Nonmethane Hydrocarbons in Ambient Air of Hazy and Normal Days in Foshan, South China

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 2012 Apr; 29(4): 262–269.

PMCID: PMC3313607
PMID: 22493559

Nonmethane Hydrocarbons in Ambient Air of Hazy and Normal Days in Foshan, South China

Abstract

A first study of nonmethane hydrocarbons (NMHCs) on hazy and normal days was performed in Foshan for providing deep insight into the local deteriorating air quality. Ethane, propane, i-pentane, ethene, propene, ethyne, benzene, and toluene were eight most abundant compounds, accounting for 71%–85% of total NMHCs. Most hydrocarbons showed much higher levels on hazy days than normal days together with hydrocarbon/ethyne ratios and diurnal variations, indicating hazy days are more dominated by vehicular emission. Correlation coefficients (R2) of ethane, propane, ethane, propene, benzene, and total NMHCs with ethyne were 0.62–0.83, indicating these compounds are mainly related to vehicular emission. R2 analysis indicated that solvent usage is responsible for toluene and other aromatic hydrocarbons (e.g., ethylbezene). Benzene/toluene (B/T) ratio was 0.44±0.23 during whole sampling periods, again indicating vehicular emission is the dominant source. Lower B/T ratio (0.30±0.14) on hazy days than that (0.58±0.21) on normal days suggested that solvent usage emitted toluene.

Key words: : air pollution control processes, atmospheric chemistry, air quality, haze

Introduction

Nonmethane hydrocarbons (NMHCs) are the major classes of organic pollutants and the key ozone (O3) precursors in atmosphere (Poisson et al.; Xiao and Zhu, ; Caselli et al.), which can significantly affect the atmospheric photochemical chemistry and human health (Atkinson, ; Elbir et al.; Mudliar et al.). Their sources in urban air are usually dominated by anthropogenic emissions including liquefied petroleum gas (LPG) leakage, solvent usage, and vehicular emission (Barletta et al.; Tang et al.; Duan et al.). Recent studies on NMHCs showed that they have frequently exhibited much higher levels in Pearl River Delta (PRD), a rapidly developed region as well as a highly polluted area in south China (Wang et al.; Tang et al.; Shao et al.). Although NMHCs have been widely investigated in PRD (Liu et al.; Shao et al.), for instance, leakage from vehicles fueled by LPG contributed mainly to ambient propane in Guangzhou (Tang et al.); however, much remains unclear about the behaviors of NMHCs under conditions of particular pollution episodes, for example, hazy days, which will provide us deep insight into the local air pollution.

Haze is defined as a weather phenomenon that leads to visibility of <10 km in China (CMA, ), which is formed from moisture, dust, and vapor in the atmosphere. Urban haze generally results from excessive air pollutants emitted by anthropogenic sources and gas-to-particle conversion (Watson, ; Fu et al.). Especially, haze is closely related to meteorological conditions and air pollution differing from those in normal days (Sun et al.; Mao et al.), because it is affected by the air contaminants with special characteristics (Wang et al.; Lü et al.). Recently, haze pollution has been an increasing concern among the public, scientific, and governments because of its negative impact on visibility, human health, and even the global climate (Yadav et al.; Kang et al.; Che et al.).

The growing haze and photochemical smog involving NMHCs has now become the major air pollution items in PRD region. Air pollutants such as carbonyls and particles have been studied on hazy days of Guangzhou in PRD (Lü et al.; Tan et al.); until now, very few studies on atmospheric NMHCs during haze episodes have been conducted, although hazy days often occur in the local region, particularly in winter time (Lü et al.; Tan et al.). Especially, no data on NMHCs are available in the most highly polluted city named Foshan (GDEMC, ), an intensive industrialization area in PRD. With the rapid economic development of Foshan during the past three decades, large amounts of air pollutants were released into the air and then resulted in a rapid deterioration of the local air quality. Considering that both photochemical smog involving NMHCs and haze pollution in Foshan are becoming more deteriorate now than before, the objectives of this study mainly aim at (1) studying variation characteristics of NMHCs between hazy days and normal days in Foshan and (2) providing original data of NMHCs for local environmental protection agency to manage the rapidly deteriorating air quality in Foshan.

Experimental

Site description

Foshan is the third largest city in central Guangdong province of PRD (the PRD region has a total population of 120 million people) in southern China, which experiences a humid subtropical climate. The prefectural area under the city's jurisdiction covers about 3840 km2 and a population of 5.9 million, of which 3.6 million reside in the city proper. The city has become relatively affluent compared with other cities in China and is home to many large private enterprises. Foshan has been recently the production base of leathers, ceramics, and plastic products of China, for example, its production of microwave cooker ranks first in the country. The sampling site (longitude 113°06′E and latitude 23°02′N) is located on the roof of a 10-storey building (30 m above the ground) in the urban central of Foshan, which is surrounded by residential buildings, business offices, and roads (Fig. 1).

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Location of sampling site during sampling periods in Foshan, China.

Air sampling

Hydrocarbon samples on December 6–8, 10–13, and 27–31, 2008, were collected each day at 08:30 (morning), 14:30 (afternoon), and 19:00 (evening). Hazy days (Fig. 2) demonstrated lower visibility (≤10 km), lower wind speed (WS), and higher temperature than that on normal days (Tan et al.). The samples were collected by 2-L commercial stainless steel canisters (Polar Ware Company), inside of which were electrically polished (Lü et al.). All canisters were precleaned five times using ultrapure N2 (>99.999%) and then preevacuated by a canister cleaner (Entech Instruments, Inc.; Model 3100) before sampling. Sampling was performed according to the USEPA Compendium Method To-14A (Wang et al.). A flow-controlling valve was used to collect 10 min integrated sample by slightly opening the valve, and the sampling inlet was placed at ∼1.5 m above the roof of the building, through which air was drawn by opening the valve. During sampling periods, data of traffic volume in Foshan were collected from Foshan Environmental Protection Bureau by our sampling staff to evaluate possible effects of vehicles on hydrocarbons.

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Averages of visibility, wind speed, and temperature during sampling periods.

Analysis

The analytical method has been reported in our previous studies in detail (Wang et al.; Lü et al.). Briefly, samples were concentrated in the Model 7100 preconcentrator (Entech Instruments, Inc.) and then injected into an HP6890 gas chromatography coupled to an HP5973 mass-selective detector. A RESTEK RTX-1 capillary column (60 m×0.32 mm×1.0 μm) was used in the system. The column temperature was initially held at 40°C for 2 min, then programmed at a rate of 6°C/min−1 to 230°C, and isothermal held for 5 min. Compounds were identified by their retention times and mass spectra. Standard gas mixtures (1.0 ppm; Supeclo To-14 Calibration Mix) were first dynamically diluted with zero air, then sampled, and analyzed using identical conditions to those for the field samples, and seven-point calibration (0.0, 1.0, 5.0, 10.0, 20.0, 40.0, 50.0 ppbv) was performed. During analysis, the sample volume for each injection was 250 mL, and the detection limits of the method for all compounds were <0.2 ppb. The relative deviations in the duplicate samples were ≤5%, for example, it was 2% for alkanes and 5% for alkenes.

Results and Discussion

Concentrations

To evaluate pollution levels of hydrocarbons between hazy days and normal days in Foshan, a total of 24 hydrocarbons were measured for data comparison (hazy days vs. normal days) during sampling periods (Table 1). Total NMHCs ranged from 96 to 342 ppbv with a mean of 175.16±66.97 ppbv on hazy days, whereas it ranged from 39 to 128 ppbv (with a mean of 76.96±21.24 ppbv) on normal days. On both hazy and normal days, ethane, propane, i-pentane, ethene, propene, ethyne, benzene, and toluene are the eight most abundant hydrocarbons, accounting for 71%–85% of total NMHCs (Table 1).

Table 1.

Concentrations (ppbv) of Hydrocarbons, O3, and NO2 During Sampling Periods in Foshan, China

 
Hazy days (December 10–13 and 27–28, 2008)
Normal days (December 6–8 and 29–31, 2008)
HydrocarbonsMorningaAfternoonaEveningaMeanbMin.cMax.cMorningaAfternoonaEveningaMeanbMin.cMax.c
Ethane22.71±9.4711.95±6.1716.57±8.3117.08±8.867.6138.4711.95±3.148.69±1.7811.67±3.2810.77±3.055.5317.12
Propane17.50±7.4913.14±4.1116.22±3.6915.62±5.397.5729.0110.34±1.218.86±1.2411.33±2.4110.18±1.926.5614.32
n-Butane5.68±1.873.49±1.174.42±1.374.53±1.682.249.002.27±0.601.83±0.622.40±0.982.17±0.750.743.73
i-Butane5.32±2.243.14±1.234.39±1.154.28±1.781.858.481.97±0.581.35±0.652.00±1.001.77±0.780.233.81
n-Pentane1.65±1.240.79±0.511.61±1.081.35±1.020.144.050.71±0.330.66±0.501.17±0.710.85±0.550.112.48
i-Pentane14.91±8.3730.99±10.6718.49±12.7221.46±12.335.2843.376.11±6.696.84±2.996.27±3.646.41±4.451.6119.20
Cyclopentane0.35±0.170.26±0.100.36±0.140.32±0.140.050.560.15±0.120.15±0.090.26±0.110.19±0.120.050.43
n-Hexane2.09±1.633.99±6.092.41±1.572.83±3.620.6016.260.94±0.830.79±0.522.66±4.461.47±2.630.2311.75
Cyclohexane0.50±0.370.27±0.180.57±0.500.45±0.380.081.520.16±0.090.16±0.140.77±1.240.36±0.740.063.28
n-Heptane2.15±2.080.55±0.412.44±2.401.71±1.940.186.020.31±0.160.32±0.370.66±0.620.43±0.430.091.83
n-Octane2.34±1.811.18±1.003.34±2.322.29±1.910.377.010.29±0.100.31±0.130.64±0.440.41±0.310.201.24
Total alkanesd75.18±27.7169.74±22.6370.82±23.1671.91±23.2438.37117.8135.20±3.1329.95±5.4039.83±12.5535.00±8.6624.2262.36
Ethene30.65±18.4016.59±3.6432.74±7.5626.66±13.2211.2164.9813.83±6.6110.03±4.6916.66±6.2513.51±6.211.4926.24
Propene10.04±5.765.20±2.7910.90±3.108.71±4.642.0218.205.12±1.653.59±1.646.24±3.174.99±2.411.4410.38
i-Butene2.65±1.701.56±0.663.28±1.842.50±1.590.846.101.42±0.461.10±0.841.59±0.931.37±0.750.462.91
trans-2-Butene0.99±0.730.37±0.221.29±0.460.88±0.620.122.080.32±0.080.27±0.090.45±0.200.35±0.150.140.70
cis-2-Butene0.70±0.500.28±0.110.87±0.450.62±0.450.121.500.27±0.090.23±0.100.44±0.250.31±0.180.130.78
Isoprene0.37±0.260.37±0.110.60±0.130.45±0.200.150.810.22±0.070.26±0.170.30±0.160.26±0.130.060.57
trans-2-Pentene0.55±0.310.16±0.080.47±0.310.39±0.300.080.900.15±0.060.14±0.090.24±0.180.18±0.120.030.52
Total alkenesd45.95±26.3424.52±7.0250.15±11.7740.21±19.8215.4893.7521.35±7.5415.62±6.3825.92±9.7120.97±8.674.9438.67
Ethyne36.12±15.7425.68±8.6435.30±13.0532.36±12.9918.3164.1013.51±2.8011.91±2.9114.62±3.7313.35±3.197.0319.76
Benzene5.61±4.583.66±3.388.08±2.985.78±3.951.2414.291.89±0.642.18±1.232.92±1.062.33±1.040.444.16
Toluene20.28±10.1110.29±5.5119.77±8.9016.78±9.205.1334.783.98±2.433.21±1.434.02±2.323.74±2.021.407.95
Ethylbenzene5.60±5.721.88±1.755.55±4.024.34±4.300.4313.060.92±1.010.45±0.180.87±0.690.75±0.700.212.81
m-/p-Xylene2.71±2.471.09±1.433.57±1.992.46±2.170.145.970.67±0.630.29±0.130.62±0.450.53±0.460.131.63
o-Xylene1.69±1.710.57±0.631.68±1.161.31±1.290.104.310.35±0.350.22±0.150.35±0.280.30±0.260.061.00
Total aromaticsd35.89±23.5217.48±11.9738.65±16.9930.67±19.587.0467.297.82±4.856.35±3.028.78±4.577.65±4.102.9016.41
Total NMHCsd193.14±90.75137.42±39.20194.92±53.96175.16±66.9795.97342.9577.88±11.3463.83±15.4789.16±27.9276.96±21.2439.09128.07
NO2e13.31±4.0013.39±6.1520.05±9.8515.58±7.417.3032.1430.92±17.4327.43±18.1518.34±18.2925.57±16.376.3363.30
O3e4.71±3.7033.29±14.253.27±0.9013.75±16.320.4746.675.68±4.7425.36±3.933.12±0.8911.38±10.771.4031.27
aThe arithmetic mean and standard deviation for data collected from the same sampling duration.
bThe total arithmetic mean and standard deviation for all data on hazy or normal days.
cThe minimum (Min.) (or the maximum [Max.]) value of data on hazy or normal days.
dTotal alkanes, total alkenes, total aromatics, and total NMHCs were the sum of the listed alkanes, alkenes, aromatics, and all hydrocarbon concentrations, respectively.
eData of O3 and NO2 concentrations were collected from Foshan Environmental Protection Bureau (EPB), Foshan.

NMHC, nonmethane hydrocarbon.

As shown in Table 1, the concentrations of most hydrocarbons on hazy days were higher than that on normal days, for example, ethyne increased by ∼142% from normal days to hazy days. The variation trends of hydrocarbons have also been observed for other air pollutants such as carbonyls and particles between hazy days and normal days in Guangzhou (Lü et al.; Tan et al.), indicating that hazy days represent more serious pollution of hydrocarbons than normal days. Data of evaluated O3 levels on hazy days (13.75 ppbv) and normal days (11.38 ppbv) (Table 1) suggested that hazy days are more oxidative, which will likely lead to much more losses of hydrocarbons on hazy days. The observed higher levels of NMHCs on hazy days might be due to accumulation of hydrocarbons under steady weather conditions, for example, lower visibility and WS on hazy days (Fig. 2).

Diurnal patterns

Most hydrocarbons showed higher levels in the morning and evening, especially on hazy days (Table 1), for example, ethyne on hazy days decreased by ∼30% from morning to afternoon and then increased by ∼37% from afternoon to evening. This diurnal variation pattern (Fig. 3) implied the dominant emission from vehicles, as traffic volume reaches its highest level at rush hours in the morning and evening. The lowest levels in the afternoon are also likely the results of reaction with OH and increased mixing height of the planetary boundary layer (Tang et al.). In addition, the average WS in the afternoon was higher than that in the morning (or evening) (Fig. 2), resulting in stronger ventilation and then diluting the air pollutants. However, i-pentane, a marker for gasoline evaporation (Barletta et al.), exhibited the highest levels (30.99±10.67 ppbv) in the afternoon, especially on hazy days. The higher temperature in the afternoon than in the morning (or evening) (Fig. 2) is conducive to evaporation of solvent containing i-pentane, which was supported by the highest level of i-pentane occurring in the afternoon (Fig. 3).

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Mean diurnal variations of abundant hydrocarbons during sampling periods.

Averagely, alkanes, alkenes, and aromatic hydrocarbons accounted for 36%–51%, 18%–26%, and 12%–19% of total NMHCs on hazy days (they were 45%–48%, 23%–29%, and 9%–10% on normal days), respectively (Table 1). On hazy days, ethyne contributed first (19%), followed by ethene (15%), i-pentane (14%), ethane (10%), toluene (9%), propane (9%), propene (5%), and benzene (3%). On normal days, ethyne contributed first (18%), followed by ethene (17%), ethane (14%), propane (14%), i-pentane (9%), propene (6%), toluene (5%), and benzene (3%). Considering that ethyne is a tracer for vehicular exhaust (Barletta et al.), i-pentane is a marker for gasoline evaporation, and toluene is emitted from vehicles, painting, and industrial processes (solvent usage) (Barletta et al.), the contribution ranking of these abundant compounds to total NMHCs was closely associated with vehicular emission, gasoline evaporation, and solvent application. Especially, the concentration of toluene in total NMHCs showed the largest distinction between hazy days and normal days compared with other seven abundant compounds. This might be due to different meteorological conditions (Fig. 2) and different photochemical activities of toluene (Atkinson, ) in the two day types.

Levels in relation to meteorology

Meteorological conditions can affect air pollutants and have been long recognized as being associated with the worst air pollution episodes (Lü et al.; Tan et al.). Figure 4 plots the relationships of total NMHCs with visibility and WS. On hazy days, total NMHCs did not show clear variation trends under lower visibility conditions (0–5 km), but it decreased with the increasing of visibility when visibility was 5–10 km. Total NMHCs also showed no statistical variation trend together with WS being ≤2 m/s for most samples on hazy days (Fig. 4), indicating that the dilution effect of WS on hydrocarbons is negligible on hazy days. In addition, no clear boundaries were observed for both relative humidity (RH) and temperature between hazy days and normal days, and RH ranged from 40% to 90% for most samples during sampling periods (Fig. 4). On the whole, hazy days demonstrated lower visibility, lower WS (≤2 m/s), and higher levels of hydrocarbons compared with normal days in this study.

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Meteorological conditions in relation to total NMHCs during sampling periods. NMHC, nonmethane hydrocarbon.

Sources of hydrocarbons

Generally, alkenes and alkynes are characteristic products of combustion engines (Barletta et al.). In urban environments, vehicular emission is by far the most important source (Tang et al.), which has been supported by the highest level of ethyne (a tracer for vehicular emission) in this study (Table 1). To assess the impact of vehicles on hydrocarbon levels, mean hydrocarbon/ethyne ratios were calculated for individual hydrocarbons between hazy days and normal days (Fig. 5). It was expected that the lower hydrocarbon/ethyne ratios mean that air hydrocarbons are more dominated by vehicular emission. For most hydrocarbons, the hydrocarbon/ethyne ratios on hazy days were approximately less than those in normal days, although traffic volume showed no significant differences in the two day types (Fig. 5), indicating vehicular emission is more dominant on hazy days. However, toluene exhibited significant higher ratios on hazy days, likely suggesting additional source differing from vehicles, because toluene is also emitted from solvent usage including painting, printing, and dry cleaning (Na et al.; Yan et al.).

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Variations of traffic volume and mean hydrocarbon/ethyne ratio during sampling periods.

To clearly identify the influence of vehicular emission on ambient hydrocarbons, correlation coefficients (R2) of abundant hydrocarbons with ethyne are calculated in Table 2. Ethane, propane, ethane, propene, and benzene showed good correlations (R2=0.62–0.83) with ethyne, indicating that their sources are mainly vehicular emission; the R2 of total NMHCs with ethyne was 0.76–0.79, indicating that ambient hydrocarbons are mainly related to vehicles. Especially, R2 of propane with ethyne (R2=0.62) on hazy days were significantly lower than that (R2=0.83) on normal days (Table 2), suggesting the more intensive photochemical activity of propane (Atkinson, ) on hazy days compared with normal days.

Table 2.

Correlation Coefficients (R2) of Hydrocarbons with Ethyne and Toluene

 
R2 with ethyne
 
R2 with toluene
HydrocarbonsHazy daysNormal daysHydrocarbonsHazy daysNormal days
Ethane0.620.65Benzene0.530.48
Propane0.620.83Ethylbezene0.780.84
Ethene0.660.63m/p-Xylene0.790.85
Propene0.660.76o-Xylene0.700.81
Benzene0.670.73Total aromatics0.930.98
Toluene0.490.55   
Total NMHCs0.760.79   

Toluene is emitted from both vehicular emission and solvent usage (painting, printing, dry cleaning, etc.) (Klimont et al.; Na et al.; Yan et al.), and most of the solvents did not contain benzene (Na et al.). In this study, abundant toluene showed weak correlation (R2=0.48–0.55) with benzene and ethyne, leading us to believe that ambient toluene could be used as a reliable marker for solvent usage during sampling periods. As can be seen in Table 2, ethylbezene, m/p-xylene, and o-xylene showed good correlations (R2=0.70–0.85) with toluene, indicating they mainly come from a similar source as that of toluene, for example, solvent usage. Especially, R2 of ethylbezene, m/p-xylene, and o-xylene with toluene on normal days were higher than that on hazy days. This may be explained by more intensive photochemical activity of toluene on hazy days. Generally, radiation can be weaker because of scattering by haze and oxidants may be titrated by the high concentration of hydrocarbons as well as active nitrogen oxides such as nitric oxide (Atkinson, ) on hazy days. In this study, O3 levels during sampling periods in Foshan were used to evaluate the oxidative activities of toluene between hazy days and normal days, because O3 is the crucial intermediate species in photochemical reactions of ambient hydrocarbons and represents the major photochemical oxidant in the atmosphere. As can be seen in Table 1, the mean O3 levels in the morning (or evening) on hazy days were approximately equal to those on normal days. However, in the afternoon, hazy days showed much higher levels of O3 (33.29 ppbv) than normal days (25.36 ppbv). Therefore, hazy days in this study are considered to be more intensive oxidation than normal days, resulting in weaker correlations of toluene with these aromatic hydrocarbons. Moreover, total aromatics showed rather good correlation with toluene (R2=0.93–0.98), indicating ambient aromatic hydrocarbons are mainly related to the same source as that of toluene.

To further differentiate vehicular emission and other combustion sources, the benzene-to-toluene ratio (B/T) was considered. A B/T ratio of ∼0.5 (wt/wt) was reported to be characteristic of vehicular emission (Barletta et al.), and higher B/T ratios represented the sources from burning of biofuel, charcoal, and coal (Duan et al.). During whole sampling periods, the mean B/T ratio was 0.44±0.23, indicating the dominant emission from vehicles. On hazy days, the B/T ratios (a mean of 0.30±0.14) were 0.23±0.12 in the morning, 0.29±0.17 in the afternoon, and 0.37±0.10 in the evening; on normal days, they were 0.47±0.13 in the morning, 0.57±0.24 in the afternoon, and 0.70±0.22 in the evening (with a mean of 0.58±0.21 on normal days). In this study, ambient hydrocarbons on hazy days are mainly dominated by vehicular emission, which may raise the B/T ratio on hazy days compared with normal days, because benzene was mainly emitted from vehicles as discussed earlier. The rate constants (kOH) for gas-phase reactions of OH radical with benzene and toluene are 1.23×1012 and 5.95×1012 cm−3·molecule−1·s−1, respectively (Yassaa et al.). Then, the faster removal rate of toluene under conditions of more intensive oxidation may also raise the B/T ratios on hazy days. However, the measured mean B/T value (0.30) on hazy days was much lower than that (0.58) on normal days. The observed significant difference of measured mean B/T ratios between hazy days and normal days suggests the following fact. The lower WS, weaker air convection, and weaker atmospheric diffusion on hazy days (Fig. 2) might be more prone to accumulations of toluene with high levels compared with low levels of benzene. The difference was more likely to benefit from solvent usage emitting toluene based on the R2 analysis above, resulting in the reduction of B/T values on hazy days, because a large amount of trades involving painting, printing, and dry cleaning are very well developed in Foshan.

Conclusions

Ethane, propane, i-pentane, ethene, propene, ethyne, benzene, and toluene are eight most abundant hydrocarbons on hazy and normal days of Foshan, accounting for 71%–85% of total NMHCs. Concentrations of most hydrocarbons on hazy days were greater than that on normal days together with diurnal variations and the hydrocarbon/ethyne ratios, indicating that hazy days are more dominated by vehicles than normal days. R2 analysis indicated that ethane, propane, ethane, propene, benzene, and total NMHCs are mainly related to vehicular emission, whereas solvent usage is responsible for toluene and other aromatic hydrocarbons. The mean B/T ratio was 0.44±0.23 during whole sampling periods, again indicating the dominant vehicular emission. The mean B/T ratio showed a lower value (0.30±0.14) on hazy days than that (0.58±0. 21) on normal days, suggesting that solvent usage emitted toluene during sampling periods.

Acknowledgments

The authors acknowledge the research support by Knowledge Innovation Program of the Chinese Academy of Sciences (Grant No. XMXX280732) and State Key Joint Laboratory of Environment Simulation and Pollution Control (10K13ESPCT). The authors are thankful to all staff for participating in air sampling. The authors thank Professor X.M. Wang and his group at State Key Laboratory Organic Geochemistry (China) for analyzing the air samples. Especially, the authors sincerely appreciate anonymous reviewers for their constructive criticisms and positive comments on this article.

Author Disclosure Statement

No competing financial interests exist.

References

  • Atkinson R. Atmospheric chemistry of VOCs and NOxAtmos. Environ. 2000;34:2063. []
  • Barletta B. Meinardi S. Rowland F.S. Chan C.Y. Wang X.M. Zou X.C. Chan L.Y. Blake D.R. Volatile organic compounds in 43 Chinese cities. Atmos. Environ. 2005;39:5979. []
  • Barletta B. Meinardi S. Simpson I.J. Khwaja H.A. Blake D.R. Rowlandm F.S. Mixing ratios of volatile organic compounds (VOCs) in the atmosphere of Karachi, Pakistan. Atmos. Environ. 2002;36:3429. []
  • Caselli M. de Gennaro G. Marzocca A. Trizio L. Tutino M. Assessment of the impact of the vehicular traffic on BTEX concentration in ring roads in urban areas of Bari (Italy) Chemosphere. 2010;81:306. [PubMed[]
  • Che H. Zhang X. Li Y. Zhou Z. Qu J.J. Hao X. Haze trends over the capital cities of 31 provinces in China, 1981–2005. Theor. Appl. Climatol. 2009;97:235. []
  • China Meteorological Administration (CMA) Specification of Surface Meteorological Observation, Beijing. Beijing: China Meteorological Press; 2003. p. 21. (in Chinese). []
  • Duan J. Tan J. Yang L. Wu S. Hao J. Concentration, sources and ozone formation potential of volatile organic compounds (VOCs) during ozone episode in Beijing. Atmos. Res. 2008;88:25. []
  • Elbir T. Cetin B. Cetin E. Bayram A. Odabasi M. Characterization of volatile organic compounds (VOCs) and their sources in the air of Izmir, Turkey. Environ. Monit. Assess. 2007;133:149. [PubMed[]
  • Fu Q. Zhuang G. Wang J. Xu C. Huang K. Li J. Hou B. Lu T. Streets D.G. Mechanism of formation of the heaviest pollution episode ever recorded in the Yangtze River Delta, China. Atmos. Environ. 2008;42:2023. []
  • Guangdong Province Environmental Protection Monitoring Center (GDEMC) Pearl River Delta Regional Air Quality Monitoring Network, A Report of Monitoring Results in 2006. Guangzhou, China: Guangdong Province Press; 2008. []
  • Kang C.M. Lee H.S. Kang B.W. Lee S.K. Sunwoo Y. Chemical characteristics of acidic gas pollutants and PM2.5 species during hazy episodes in Seoul, South Korea. Atmos. Environ. 2004;38:4749. []
  • Klimont Z. Streets D.G. Gupta S. Cofala J. Lixin F. Ichilawa Y. Anthropogenic emissions of non-methane volatile organic compounds in China. Atmos. Environ. 2002;36:1309. []
  • Liu Y. Shao M. Lu S. Chang C. Wang J. Fu L. Source apportionment of ambient volatile organic compounds in the Pearl River Delta, China: Part II. Atmos. Environ. 2008;42:6261. []
  • Lü H. Cai Q. Wen S. Chi Y. Guo S. Sheng G. Fu J. Antizar-Ladislao B. Carbonyl compounds in the ambient air of hazy days and clear days in Guangzhou, China. Atmos. Res. 2009;94:363. []
  • Lü H. Wen S. Feng Y. Wang X. Bi X. Sheng G. Fu J. Indoor and outdoor carbonyl compounds and BTEX in the hospitals of Guangzhou, China. Sci. Total Environ. 2006;368:574. [PubMed[]
  • Mao T. Wang Y. Jiang J. Wu F. Wang M. The vertical distributions of VOCs in the atmosphere of Beijing in autumn. Sci. Total Environ. 2008;390:97. [PubMed[]
  • Mudliar S. Giri B. Padoley K. Satpute D. Dixit R. Bhatt P. Pandey R. Juwarkar A. Vaidya A. Bioreactors for treatment of VOCs and odours: A review. J. Environ. Manage. 2010;91:1039. [PubMed[]
  • Na K. Kim Y.P. Moon K.C. Diurnal characteristics of volatile organic compounds in the Seoul atmosphere. Atmos. Environ. 2003;37:733. []
  • Poisson N. Kanakidou M. Crutzen P.J. Impact of nonmethane hydrocarbons on tropospheric chemistry and the oxidizing power of the global troposphere: 3-dimensional modelling results. J. Atmos. Chem. 2000;36:157. []
  • Shao M. Zhang Y. Zeng L. Tang X. Zhang J. Zhong L. Wang B. Ground-level ozone in the pearl river delta and the roles of VOC and NOx in its production. J. Environ. Manage. 2009;90:512. [PubMed[]
  • Sun Y.L. Zhuang G.S. Tang A.H. Wang Y. An Z.S. Chemical characteristics of PM2.5 and PM10 in haze-fog episodes in Beijing. Environ. Sci. Technol. 2006;40:3148. [PubMed[]
  • Tan J. Duan J. Chen D. Wang X. Guo S. Bi X. Sheng G. He K. Fu J. Chemical characteristics of haze during summer and winter in Guangzhou. Atmos. Res. 2009;94:238. []
  • Tan J.H. Bi X.H. Duan J.C. Kenneth A.R. Sheng G.Y. Fu J.M. Seasonal variation of particulate polycyclic aromatic hydrocarbons associated with PM10 in Guangzhou, China. Atmos. Res. 2006;80:250. []
  • Tang J.H. Chan L.Y. Chan C.Y. Li Y.S. Chang C.C. Liu S.C. Wu D. Li Y.D. Characteristics and diurnal variations of NMHCs at urban, suburban, and rural sites in the pearl river delta and a remote site in South China. Atmos. Environ. 2007;41:8620. []
  • Wang X.M. Sheng G.Y. Fu J.M. Urban roadside aromatic hydrocarbons in three cities of the Pearl River delta, People's Republic of China. Atmos. Environ. 2002;36:5141. []
  • Wang Y. Zhuang G. Sun Y. An Z. The variation of characteristics and formation mechanisms of aerosols in dust, haze, and clear days in Beijing. Atmos. Environ. 2006;40:6579. []
  • Watson J.G. Visibility: Science and regulation. J. Air Waste Manage. Assoc. 2002;52:628. [PubMed[]
  • Xiao H. Zhu B. Modeling study of photochemical ozone creation potential of non-methane hydrocarbon. Water Air Soil Pollut. 2003;145:3. []
  • Yadav A.K. Kumar K. Kasim A. Singh M.P. Parida S.K. Sharan M. Visibility and incidence of respiratory diseases during the 1998 haze episode in Brunei Darussalam. Pure Appl. Geophys. 2003;160:265. []
  • Yan B. Shao M. Lu S. Wang B. Source profiles of volatile organic compounds associated with solvent use in Beijing, China. Atmos. Environ. 2010;44:1919. []
  • Yassaa N. Brancaleoni E. Frattoni M. Ciccioli P. Isomeric analysis of BTEXs in the atmosphere using β-cyclodextrin capillary chromatography coupled with thermal desorption and mass spectrometry. Chemosphere. 2006;63:502. [PubMed[]

PM urges citizens to join Shramdaan on Oct 1, 2023

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PM urges citizens to join Shramdaan on Oct 1, 2023

Posted On: 29 SEP 2023 10:12AM by PIB Delhi

The Prime Minister, Shri Narendra Modi has urged citizens to join the Shramdaan, a cleanliness initiative as part of Swachh Bharat on 1st October 2023 at 10 AM. 

Sharing a post on X by Swachh Bharat Urban, the Prime Minister said;

“1st October at 10 AM, we come together for a pivotal cleanliness initiative. 

A Swachh Bharat is a shared responsibility, and every effort counts. Join this noble endeavour to usher in a cleaner future.”

EPFO extends three months’ time for Employers to upload wage details etc. regarding Pension on Higher Wages

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EPFO extends three months’ time for Employers to upload wage details etc. regarding Pension on Higher Wages

Posted On: 29 SEP 2023 6:00PM by PIB Delhi

Earlier an online facility was made available by EPFO for submitting Applications for Validation of Option /Joint Options for pension on higher wages. The facility was for eligible pensioners / members in compliance with the Hon’ble Supreme Court order dated 04.11.2022. The facility was launched on 26.02.2023 and was to remain available only till 03.05.2023. However, considering the representations of the employees, the time limit was extended to 26.06.2023 in order to provide complete four months’ time to eligible pensioners / members for filing applications.

A last opportunity of 15 days was further given to remove any difficulty faced by the eligible pensioners/ members. Accordingly, the last date for submission of Applications for Validation of Option / Joint Options by employees was extended to 11.07.2023.  17.49 lakh Applications for Validation of Option / Joint Options have been received from pensioners / members till 11.07.2023.

In view of representations received from Employers & Employers’ Associations wherein requests were made to extend time period for uploading wage details of applicant pensioners / members, the employers were also given further period of three months to submit wage details etc. online latest by 30.09.2023.

Now, again many representations have been received from Employers & Employers’ Associations wherein requests have been made to extend further time period for uploading wage details of applicant pensioners / members. 5.52 lakh Applications for Validation of Option / Joint Options are still pending with employers, as on 29.09.2023.

Therefore, the request has been considered sympathetically and the Chairman, Central Board of Trustees has extended the time, for the employers to submit wage details etc till 31.12.2023.

Newly designed ammonia receiver

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https://ureaknowhow.com/newly-designed-ammonia-receiver/

WHY WE ARE ADDING AIR TO OFF GAS

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 The air given to HD & HDR (High pressure de composer & HD Re boiler) by GB 401 (Blower) for Passivation of the stainless steel and different equipment for passivation

pbaboo
Participant
    • Expert
    Offline
    Registered On: August 8, 2014
    Topics: 1
    Replies: 935

    Dear Sravan Kumar,
    Your Process is MTC so, the whole air given to CO2 compressor in suction line for passivation. Your process is conventional type means you have no stripper. The passivation air should be just sufficient for passivation because finally all the inerts vent out through M.P. section along with inerts some amount of ammonia also loosed through it.
    In non-conventional or stripping process some amount of air given to stripper bottom for bottom dome passivation however Titanium stripper not required additional air for passivation some dissolved oxygen is sufficient for passivation.
    The CO2 having some amount of Hydrogen so the chances of explosion in MP section.
    There are following manner to avoid explosive mixture
    1. To remove Hydrogen in CO2 Compressor.
    2. To add NG in MP condenser (in case of recovery of inerts gas as fuel.)
    3. To add steam in MP vents d/s if inerts gas not recovered (vent to B/D)
    Danger of Choking Burner in case of recovering inerts as a fuel,
    The NG is having some amount of CO2 (2-5% depends upon source), so the Carbonate/Carbamate formation takes place and resulted choking of burner to avoid this phenomenon Some separate burner to be used for inerts fuel don’t mixed with NG.
    Some plants recovers these inerts as a fuels.
    If you remove Hydrogen in CO2 compressor then No question from recovering fuel because fuel (Hydrogen) already remove from Compressor.

    Shri Bhupender Yadav leads the cleanliness drive under the Swachchta Hi Seva campaign

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    Shri Bhupender Yadav leads the cleanliness drive under the Swachchta Hi Seva campaign


    People across India are joining the Swachh Bharat Abhiyan turning it into a Jan Andolan on the clarion call given by Prime Minister : Shri Yadav

    Posted On: 01 OCT 2023 4:45PM by PIB Delhi

    Union Minister of Environment, Forest and Climate Change and Labour and Employment  Shri Bhupender Yadav lead the cleanliness drive under the Swachchta Hi Seva campaign of the Ministry of Environment, Forest and Climate Change at

    National Zoological Park (NZP), New Delhi .

     

    Smt.Leena Nandan,Secretary MoEF&CC , Sh. C.P. Goyal, DGF&SS, MoEF&CC, Sh. Bivash Ranjan, ADG (WL), MoEF&CC,Shri Sanjay Shukla Member Secretary Central zoo authority and Joint Secretary Shri Satyajit Mishra were present on the occasion . Over 200 participants, including enthusiastic students,visitors gathered to contribute to this significant endeavor.

     

    The highlight of the day was participation of youth in the Swachhata campaign and cleaning initiatives of zoo for water body cleaning. The activity was followed by the inauguration of a PET bottle collection point, a pivotal step towards making zoo a Single-Use Plastic (SUP) free zone. This initiative underscores NZP's unwavering commitment to environmental sustainability and minimizing its ecological footprint.

    In a heartwarming gesture, Shri Bhupender Yadav distributed eco-friendly reusable bags to students, emphasizing the importance of sustainable living and environmental consciousness.

    Following the distribution of bags, an animal journal was unveiled to promote Lifestyle for Environment and cleanliness in zoo fostering an educational connection with the diverse wildlife at NZP.

    The Shramdaan activity at NZP, under the Swachchta Hi Seva campaign, demonstrates that when communities come together with a shared vision, meaningful change can be achieved. NZP remains steadfast in its commitment to wildlife conservation and environmental protection.

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    PLANT NUTRITION

    SOILS OF INDIA

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    1. Alluvial Soil

    - State: Punjab, Haryana, Uttar Pradesh, Bihar, Jharkhand
    - Composition: Rich in phosphorus, potash, and lime; deficient in nitrogen
    - Crops Grown: Wheat, rice, sugarcane, cotton, jute
    2. Black (Regur) Soil
    - State: Deccan plateau, Krishna and Godavari valleys, Andhra Pradesh, Madhya Pradesh, Tamil Nadu
    - Composition: Rich in iron, lime, aluminium, magnesium, calcium; lacks nitrogen, phosphorus, and humus
    - Crops Grown: Cotton, sugarcane, jowar, tobacco, wheat, rice
    3. Red Soil
    - State: Eastern parts of Deccan Plateau, Tamil Nadu, Goa, Odisha, Meghalaya
    - Composition: Rich in iron and potash; deficient in lime, nitrogen, phosphorus, and humus
    - Crops Grown: Wheat, rice, cotton, sugarcane, pulses
    4. Laterite Soil
    - State: Summits of Eastern and Western Ghats, Assam hills, Andhra Pradesh, Karnataka, West Bengal, Odisha
    - Composition: Rich in iron; poor in silica, lime, phosphorus, potash, humus
    - Crops Grown: Tea, coffee, rubber, cashew, millets
    5. Desert Soil
    - State: West and North-West India, Rajasthan, North Gujarat, Southern Punjab
    - Composition: Rich in soluble salts; deficient in organic matter
    - Crops Grown: With irrigation, drought-resistant crops like millets, barley, cotton, maize, pulses
    6. Mountain Soil
    - State: Hills of Jammu and Kashmir, Uttarakhand, Assam hills
    - Composition: Rich in iron and humus; deficient in lime
    - Crops Grown: With fertilizers, tea, fruits, medicinal plants
    7. Saline and Alkaline Soil
    - State: Drier parts of Bihar, Jharkhand, Uttar Pradesh, Haryana, Punjab, Rajasthan, Maharashtra
    - Composition: Contains salts like sodium, magnesium, calcium
    - Not suitable for agriculture
    8. Peaty and Marshy Soil
    - State: Kerala, coastal regions of Odisha, Tamil Nadu, Sunderbans of West Bengal
    - Composition: Contains soluble salts, and organic matter; lacks potash and phosphates
    - Crops Grown: Rice and jute cultivation
    Copied -Ayussh Sanghi

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    Greenko is one of India’s leading Renewable Energy companies

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    Vision
    Vision :
    Play Arrow“To lead Decarbonization, Digitalization and Decentralization of India's Energy Sector”
    Mission :
    Play ArrowBuild and operate flexible utility scale energy assets to deliver demand driven solutions.
    Play ArrowContinuously innovate to deliver best-in-class solutions with life cycle focus.
    Play ArrowManage all assets sustainably, leveraging leading-edge technologies.
    Play ArrowBuild public-private-people alliances for sustainable development.

    Creating an ecosystem of inclusive
    renewable assets in diverse environments.

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    PLANTS

    1607 MWp

    OPERATING
    CAPACITY

    4

    PLANTS

    1319 MWp

    OPERATING
    CAPACITY

    28

    PLANTS

    1312 MWp

    OPERATING
    CAPACITY

    55

    PLANTS

    2916 MWp

    OPERATING
    CAPACITY

    THE EVOLUTION OF GREENKO (GKO)

    milestones

    ACHIEVEMENTS AND RECOGNITION

    Notification issued for Green Credit Program (GCP) and Ecomark scheme Under LiFE Initiative to Promote Sustainable Lifestyle and Environmental Conservation

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    Notification issued for Green Credit Program (GCP) and Ecomark scheme Under LiFE Initiative to Promote Sustainable Lifestyle and Environmental Conservation

    Posted On: 13 OCT 2023 6:52PM by PIB Delhi

    To take ahead the 'LiFE' - 'Lifestyle for Environment' movement announced by the Hon’ble Prime Minister in 2021, the Ministry of Environment, Forest and Climate Change has introduced two pioneering initiatives that indicate the country's pro-active approach to climate change, sustainability and promotion eco-conscious practices. These initiatives, the Green Credit Program (GCP) and the Ecomark Scheme, seek to encourage environmentally friendly practices rooted in tradition and conservation; reflecting the ideas of LiFE  concept.
    Green Credit Program (GCP): Incentivizing Environmental Actions
    Green Credit Program (GCP )notified on 13th October, 2023 is an innovative market-based mechanism designed to incentivize voluntary environmental actions across diverse sectors, by various stakeholders like individuals, communities, private sector industries, and companies. The GCP's governance framework is supported by an inter-ministerial Steering Committee and The Indian Council of Forestry Research and Education (ICFRE) serves as the GCP Administrator, responsible for program implementation, management, monitoring, and operation.
    In its initial phase, the GCP focuses on two key activities: water conservation and afforestation. Draft methodologies for awarding Green Credits have been developed and will be notified for stakeholder consultation. These methodologies set benchmarks for each activity/process, to ensure environmental impact and fungibility across sectors. A user-friendly digital platform will streamline the processes for registration of projects, its verification, and issuance of Green Credits. The Green Credit Registry and trading platform, being developed by ICFRE along with experts, would facilitate the registration and thereafter, the buying and selling of Green Credits.
    To obtain Green Credits, individuals and entities must register their activities through the central government's dedicated app/website www.moefcc-gcp.in. The Administrator will verify the activity through a designated agency, with self-verification for small projects. Once verification is complete, the Administrator will grant a Green Credit certificate which will be tradable on the green credit platform.
    Ecomark Scheme: Promoting Eco-Friendly Products
    The philosophy behind LiFE, (Lifestyle for Environment)is nudging individual choices and behavior towards sustainability.  In line with this approach, the MoEF&CC has recast its Ecomark notification so that consumers are able to make choices among products and thereby opt for those products that are eco-friendly in their design, process etc.
    The Ecomark Scheme, notified on 13th October 2023, replaces the previous Notification. It provides accreditation and labelling for household and consumer products that meet specific environmental criteria while maintaining quality standards as per Indian norms. Products accredited under the Ecomark Scheme will adhere to specific environmental criteria, ensuring minimal environmental impact. It will build consumer awareness of environmental issues and encourage eco-conscious choices. It will also motivate manufacturers to shift towards environmentally friendly production. The scheme seeks to ensure accurate labelling and prevent misleading information about products.
    The Central Pollution Control Board administers the Ecomark Scheme in partnership with Bureau of Indian Standards (BIS), which is the national body for standards and certification.
    Both initiatives mark significant steps in promoting sustainable living, environmental conservation, and, through individual and collective choice, embody eco-friendly practices in India. They align with global sustainability goals and reflect the government's commitment to conservation and protection of the environment.
    Click here to see gazette notification 

    Click here to see gazette notification 


    WWF-India organises awareness activities during Wildlife Week 2nd-8th October under Mission LiFE

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    WWF-India organises awareness activities during Wildlife Week 2nd-8th October under Mission LiFE

    Posted On: 13 OCT 2023 1:45PM by PIB Delhi

    WWF-India, Ministry of Environment, Forest and Climate Change, (MoEF&CC) organises various awareness activities on the occasion of Wildlife Week 2nd-8th October under Mission LiFE.  The aim was to emphasise the importance of wildlife conservation and climate change in maintaining nature’s equilibrium among students of multiple schools of DelhiThe theme for this year wildlife week celebrations is "Partnerships for Wildlife Conservation".

    The mandate of Programme Centre at WWF-India, MoEF&CC is “Wildlife Conservation (including species and habitat) using geospatial techniques”. Programme Centre (PC) EIACP (Environmental Information, Awareness, Capacity Building and Livelihood Programme), Resource Partner (RP) at WWF-India was set up for collection, collation, storage, retrieval and dissemination of information in order to support and promote research, development and innovation among decision-makers, researchers, academicians, policy planners, research scientists & and other stakeholders.

     

     

    During the week, students of various schools of Delhi were briefed about the Wildlife Week, its importance and about the theme i.e., "Partnerships for Wildlife Conservation". WWF-India team also conveyed the message of Mission LiFE through a 12-minute documentary video, students and teachers also took the Pledge. The event was very impactful as after that the school children showed much interest to know more about wildlife conservation, and about combating climate change by adopting lifestyle changes in an eco-friendly manner. The target audience of approximately 864 participated in these awareness activities.

     

     

     

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    Ministry of Environment, Forest and Climate Change

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    ENVIRONMENT EXCURSION TOUR VIZAG-DELHI-HARIDWAR-RISHIKESH-MUSSOORIE-DEHRDUN-NOIDA-NEWDELHI-VIZAG -KAKINADA

    Impact of Soil Microbiome on Nutrient Cycling

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    Impact of Soil Microbiome on Nutrient Cycling
    Soil microbiomes are essential for nutrient cycling in terrestrial ecosystems. They play pivotal roles in nutrient transformations and cycling:
    1. Decomposition: Bacteria and fungi decompose organic matter, breaking it down into simpler compounds. This decomposition releases essential nutrients like nitrogen, phosphorus, and potassium, making them available for plant uptake.
    2. Nitrogen Fixation: Nitrogen-fixing bacteria convert atmospheric nitrogen (N2) into ammonium (NH4+), a plant-available form of nitrogen. This process enriches the soil with nitrogen, a critical nutrient for plant growth.
    3. Mineralization: Microbes mineralize organic nutrients, converting them into inorganic forms that plants can absorb. This includes the conversion of organic phosphorus into soluble phosphate.
    Indeed, microorganisms dwelling within the soil play an often-overlooked yet vital role in agriculture. They operate diligently in the background, tirelessly enriching soil fertility, and fortifying the overall resilience of farming ecosystems. Acknowledging and fostering this concealed force within our soils stands as a fundamental requirement for ensuring the sustainability and productivity of agriculture over the long term.
    #savesoil #soilhealth #soilscience



    Soil Testing and Nutrient Analysis

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     Soil Testing and Nutrient Analysis 



    Soil testing and nutrient analysis are foundational steps in optimizing nutrient management for healthy, high-yield crops. Here's an overview of the importance and key aspects of this topic:

    1. Significance of Soil Testing:

    Identifying Nutrient Status: Soil testing provides valuable insights into the current nutrient status of your soil, including levels of essential macronutrients (NPK) and micronutrients.

    Customized Fertilization: It allows for precise and customized fertilizer recommendations, ensuring that crops receive the nutrients they need and preventing overapplication and unnecessary costs.

    2. Nutrient Analysis:

    Macronutrients: Soil testing measures macronutrients like Nitrogen 👎, Phosphorus (P), and Potassium (K) to determine their availability to plants. This information guides the selection of appropriate fertilizers.

    Micronutrients: It also analyzes micronutrients like iron, manganese, and zinc, which are essential in smaller quantities for plant health.

    3. Steps in Soil Testing:

    Sample Collection: Soil samples are collected from various points in the field to represent the entire area accurately. Sampling depth and method are important factors.

    Laboratory Analysis: Soil samples are sent to a certified laboratory for analysis. The lab provides data on nutrient levels, pH, organic matter content, cation exchange capacity (CEC) salt concentrations among other parameters.

    Interpretation: Soil test results are interpreted to determine nutrient deficiencies or imbalances. This information informs fertilizer recommendations.

    4. Benefits of Soil Testing:

    Fertilizer Use Efficiency: Soil testing facilitates a higher fertilizer use efficiency by tailoring fertilization to the specific needs of each field or crop, minimizing waste and environmental impact.

    Cost Savings: By applying only the required nutrients, farmers can reduce fertilizer costs while maintaining or increasing yields.

    5. pH and Soil Acidity:

    Soil testing includes pH measurement, which determines soil acidity or alkalinity. Correcting pH is crucial since it affects nutrient availability. Lime may be recommended to raise pH in acidic soils, making nutrients more accessible to plants.

    6. Timing and Frequency:

    Regular soil testing is recommended, typically on an annual basis, to monitor nutrient changes over time. Timing should align with crop rotation and before each planting season.

    By understanding the significance of soil testing and nutrient analysis, farmers can make informed decisions about nutrient management. Regular soil testing, correct interpretation of results, and customized fertilization based on these findings are crucial for maintaining soil health and achieving optimal crop yields while conserving resources and protecting the environment.

    Introduction to Compressed Breathing Air

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    Introduction to Compressed Breathing Air



    Introduction to Compressed Breathing Air

    Introduction to Compressed Breathing Air

    Compressed air has many applications, including its use in Self-Contained Breathing Apparatus (SCBA). This document provides some practical information about the tests needed to guarantee SCBA Breathing Air Quality as described in the following:

     Air Composition
    Common Air Contamination Sources
    Carbon Monoxide (CO) Contamination
    Carbon Dioxide (CO2) Contamination
    Oxygen (O2) Level Control
    Total Hydrocarbon Content (THC as methane)
    Oil (Consensable Mist/Vapor) and Particulate Matter
    Water Vapor (H2O), Content, and Dew Point
    Odor Evaluation

    Air Composition

    Clean, natural air is an odorless, colorless gas mixture.  Excluding water vapor (H2O) levels, which vary greatly, three major elements make up about 99.97% of dry air: nitrogen (N2) at 78.09%, oxygen (O2) at 20.95% and argon (Ar) at 0.93%.  An important minor component of natural air is carbon dioxide (CO2) at 0.03% (300 ppm).  Trace gases in clean, natural air include: methane (CH4) at 0.0002% (2 ppm) and less than 0.0001% (1 ppm) of hydrogen (H2), nitrous oxide (N2O), ozone (O3) and some noble gases.  Synthetic air is also used in SCBA applications. This type of air is produced by blending N2 and O2 gas in the proper proportions.

    The importance of clean breathing air to sustaining life and maintaining good health is well known.  The dangers associated with breathing contaminated air are also well known and especially critical when using SCBA tanks in emergency situations.  To ensure SCBA air quality, NFPA 1404 (Sec. 7-1.1) requires a minimum CGA G-7.1 Grade D air quality, at least a 3-month air sampling schedule and a test record maintenance program. Many fire and rescue department programs have opted to use CGA G-7.1 Grade E (the minimum SCUBA grade for diving to 130 ft.) as their minimum SCBA air standard.

      Common Air Contamination Sources


    Industrial emissions, vehicle exhaust, combustion heating activities and local environmental conditions can seriously degrade the quality of intake air used during compression. Compressor equipment, malfunctions and poor maintenance or operational practices can also introduce contaminants into SCBA air tanks.

     Carbon Monoxide (CO) Contamination

    CO (a colorless, odorless gas) ranks as the most dangerous compressed air contaminant. Headaches, dizziness, unconsciousness and death can result from exposure to elevated CO levels. High-pressure compressors are often equipped with a catalyst which converts CO into much less toxic CO2. Both CGA G-7.1 Grades D and E (the most widely recognized SCBA air quality grades) list a 10 ppm maximum CO content. If a good air supply and a properly functioning, efficient compressor are in use, CO levels will be less than 1 ppm. Detectable CO levels above 1 - 2.5 ppm are abnormal and require further investigation.

     Carbon Dioxide (CO2) Contamination

    Normal CO2 levels in outdoor air (i.e. 200 - 400 ppm) or indoor air (i.e. 500 - 2,500 ppm) are not considered hazardous. However, compressed air with CO2 levels that are within the "indoor air range" can create problems in SCBA applications. Some compressors are equipped with filters to reduce CO2 levels. CGA G-7.1 lists a 1,000 ppm maximum for Grade D and a 500 ppm maximum for Grade E air. High CO2 levels in SCBA tanks can produce many of the same symptoms as CO poisoning (see above). In addition, high CO2 levels increase breathing rates, which shorten SCBA usage time. One of the most common causes of SCBA air quality failures is excessive CO2 content.

     Oxygen (O2) Level Control

    The O2 level in compressed air derived from natural or synthetic air should fall within a narrow % range. CGA G-7.1 lists an allowable 19.5 - 23.5% range for Grade D and a tighter 20 - 22% range for Grade E air. Most compressed natural air samples will have test values of 21% ± 0.5. Synthetic air samples tend to have a slightly wider, but acceptable, O2 range.

     Total Hydrocarbon Content (TH as methane)


    Several thousand types of organic gases and vapors are potentially present in air. Volatile organic contaminants can be man-made (e.g. gasoline vapor, exhaust fumes, cleaning solvents, lube oil vapor) or the result of biogenic activities (e.g. marsh gas, mold, mildew). Many organic vapors are hazardous and/or have irritating odors. A common feature of these volatile organic materials is that they contain 1 or more hydrogen (H) + carbon (C) atom. Since it is impractical to measure each type of organic contaminant present, they are measured as a group and described as a "Total Hydrocarbon Content" (TH).

    The instrument used to measure TH responds to the total amount of H+C containing molecules present. Since methane gas standards are used to calibrate this instrument, TH results are reported in "ppm v/v as methane" units. CGA G-7.1 does not list a TH limit for Grade D air, but sets a 25 ppm TH maximum for Grade E air. Clean, natural air has a TH value of about 2 ppm due to the normal presence of methane at 2 ppm. Compressed synthetic air can have TH values of less than 1 ppm. TH Values for compressed air that are greater than about 5 ppm are abnormal and require further investigation. High-pressure compressors are usually equipped with odor filters (e.g. activated charcoal filters) that remove many organic vapors. A high TH value could indicate, for example, charcoal filter saturation and the presence of lube oil degradation mist/vapors.

     Oil (Condensable Mist/Vapor) and Particulate Matter

    Air compressors, including non-lubricated models, utilize some type of lubricating fluid. Many compressors contain either mineral or synthetic lubricants (e.g. oil). Even with particle, oil and odor filters, it is still possible for oil (e.g. aerosol mist or vapor) or fine particulates (e.g. dust, dirt, powders, wear particles, pollen, spores) to contaminate SCBA air if a mechanical malfunction occurs or there has been poor maintenance. The proper sampling of compressed air for oil mist/vapor and particulates is difficult because these contaminants are not evenly distributed in the air stream and can condense on tank walls or within regulators. Re-introduction of oil mist/vapor and particulates into the air stream can occur under the right conditions.

    Sampling procedures involve connecting a filter assembly to the compressor outlet, SCBA tank or a filled sample cylinder and passing a known amount of air through the pre-weighed filter. The total weight of oil plus particulates trapped is measured in a laboratory. Both CGA G-7.1 Grades D and E list a 5 mg/m3 (0.005 mg/L = 5 ppm w/v) maximum for oil mist/vapor at Normal Temperature and Pressure (NTP = 20° [68°F] and 1 atm [14.7 psia = 101 kPa abs = 760 mm Hg]). Detectable oil levels above 0.1 - 0.3 mg/m3 are abnormal and require further investigation.

     Water Vapor (H2O) Content and Dew Point

    The dew point is the temperature at which H2O vapor will start to condense from air. This value depends upon the air's H2O vapor content and pressure. The H2O vapor content of intake air ranges from saturated to very dry. Saturation levels are in the low % range. For example, at 20°C (68°F) air can hold 2.3% H2O vapor (23,100 ppm v/v = 34 mg/L). At 40°C (104°F) this value is 6.8% (68,400 ppm v/v = 51 mg/L). The amount of H2O vapor that gets into SCBA air depends on the intake air level and filter efficiency. SCBA air is required to be dry enough to prevent malfunctions (e.g. air flow blockage) due to internal condensation or icing caused by expansion cooling past regulators. High H2O levels can also inhibit catalysts that convert CO into CO2. CGA G-7.1 does not list an H2O limit for Grade D or E air. However, SCBA air must either have a maximum H2O content of 63 ppm (0.05 mg/l), which corresponds to a -50°F dew point, or an H2O vapor maximum (ppm) resulting in a dew point that is 10°F lower than the coldest temperature expected for SCBA use. Therefore, H2O vapor limits for SCBA air are essentially dependent on the geographic region. CGA dew point limits are not pressure values but refer to "dew point over ice at 1 atm."

     Odor Evaluation


    Clean air is odorless. Many air compressors have filters to remove odors. Both CGA G-7.1 Grades D and E require that "no pronounced odor" be present in compressed air. Since the sensory response of the human nose is highly variable and extremely sensitive to certain odors, evaluation of "odor" is highly subjective. If there is a slight odor, this may be abnormal.

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