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The Montreal Protocol on Substances that Deplete the Ozone Layer

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Annex A: Controlled substances

GroupSubstanceOzone-Depleting Potential*
Group I
CFCl3(CFC‑11)1.0
CF2Cl2(CFC‑12)1.0
C2F3Cl3(CFC‑113)0.8
C2F4Cl2(CFC‑114)1.0
C2F5Cl(CFC‑115)0.6
Group II
CF2BrCl(halon‑1211)3.0
CF3Br(halon‑1301)10.0
C2F4Br2(halon‑2402)6.0
* These ozone depleting potentials are estimates based on existing knowledge and will be reviewed and revised periodically.

Annex B: Controlled substances

GroupSubstanceOzone-Depleting Potential
Group I
CF3Cl(CFC‑13)1.0
C2FCl5(CFC‑111)1.0
C2F2Cl4(CFC‑112)1.0
C3FCl7(CFC‑211)1.0
C3F2Cl6(CFC‑212)1.0
C3F3Cl5(CFC‑213)1.0
C3F4Cl4(CFC‑214)1.0
C3F5Cl3(CFC‑215)1.0
C3F6Cl2(CFC‑216)1.0
C3F7Cl(CFC‑217)1.0
Group II
CCl4carbon tetrachloride1.1
Group III
C2H3Cl3*1,1,1-trichloroethane* (methyl chloroform)0.1
* This formula does not refer to 1,1,2-trichloroethane.

Annex C: Controlled substances

GroupSubstanceNumber of isomersOzone-Depleting Potential*
Group I
CHFCl2(HCFC‑21)**10.04
CHF2Cl(HCFC‑22)**10.055
CH2FCl(HCFC‑31)10.02
C2HFCl4(HCFC‑121)20.01-0.04
C2HF2Cl3(HCFC‑122)30.02-0.08
C2HF3Cl2(HCFC‑123)30.02-0.06
CHCl2CF3(HCFC‑123)**-0.02
C2HF4Cl(HCFC‑124)20.02-0.04
CHFClCF3(HCFC‑124)**-0.022
C2H2FCl3(HCFC‑131)30.007-0.05
C2H2F2Cl2(HCFC‑132)40.008-0.05
C2H2F3Cl(HCFC‑133)30.02-0.06
C2H3FCl2(HCFC‑141)30.005-0.07
CH3CFCl2(HCFC‑141b)**-0.11
C2H3F2Cl(HCFC‑142)30.008-0.07
CH3CF2Cl(HCFC‑142b)**-0.065
C2H4FCl(HCFC‑151)20.003-0.005
C3HFCl6(HCFC‑221)50.015-0.07
C3HF2Cl5(HCFC‑222)90.01-0.09
C3HF3Cl4(HCFC‑223)120.01-0.08
C3HF4Cl3(HCFC‑224)120.01-0.09
C3HF5Cl2(HCFC‑225)90.02-0.07
CF3CF2CHCl2(HCFC‑225ca)**-0.025
CF2ClCF2CHClF(HCFC‑225cb)**-0.033
C3HF6Cl(HCFC‑226)50.02-0.10
C3H2FCl5(HCFC‑231)90.05-0.09
C3H2F2Cl4(HCFC‑232)160.008-0.10
C3H2F3Cl3(HCFC‑233)180.007-0.23
C3H2F4Cl2(HCFC‑234)160.01-0.28
C3H2F5Cl(HCFC‑235)90.03-0.52
C3H3FCl4(HCFC‑241)120.004-0.09
C3H3F2Cl3(HCFC‑242)180.005-0.13
C3H3F3Cl2(HCFC‑243)180.007-0.12
C3H3F4Cl(HCFC‑244)120.009-0.14
C3H4FCl3(HCFC‑251)120.001-0.01
C3H4F2Cl2(HCFC‑252)160.005-0.04
C3H4F3Cl(HCFC‑253)120.003-0.03
C3H5FCl2(HCFC‑261)90.002-0.02
C3H5F2Cl(HCFC‑262)90.002-0.02
C3H6FCl(HCFC‑271)50.001-0.03
GroupSubstanceNumber of isomersOzone-Depleting Potential*
Group II
CHFBr211.00
CHF2Br(HBFC-22B1)10.74
CH2FBr10.73
C2HFBr420.3-0.8
C2HF2Br330.5-1.8
C2HF3Br230.4-1.6
C2HF4Br20.7-1.2
C2H2FBr330.1-1.1
C2H2F2Br240.2-1.5
C2H2F3Br30.7-1.6
C2H3FBr230.1-1.7
C2H3F2Br30.2-1.1
C2H4FBr20.07-0.1
C3HFBr650.3-1.5
C3HF2Br590.2-1.9
C3HF3Br4120.3-1.8
C3HF4Br3120.5-2.2
C3HF5Br290.9-2.0
C3HF6Br50.7-3.3
C3H2FBr590.1-1.9
C3H2F2Br4160.2-2.1
C3H2F3Br3180.2-5.6
C3H2F4Br2160.3-7.5
C3H2F5Br80.9-1.4
C3H3FBr4120.08-1.9
C3H3F2Br3180.1-3.1
C3H3F3Br2180.1-2.5
C3H3F4Br120.3-4.4
C3H4FBr3120.03-0.3
C3H4F2Br2160.1-1.0
C3H4F3Br120.07-0.8
C3H5FBr290.04-0.4
C3H5F2Br90.07-0.8
C3H6FBr50.02-0.7
Group III
CH2BrClbromochloromethane10.12
* Where a range of ODPs is indicated, the highest value in that range shall be used for the purposes of the Protocol. The ODPs listed as a single value have been determined from calculations based on laboratory measurements. Those listed as a range are based on estimates and are less certain. The range pertains to an isomeric group. The upper value is the estimate of the ODP of the isomer with the highest ODP, and the lower value is the estimate of the ODP of the isomer with the lowest ODP.
** Identifies the most commercially viable substances with ODP values listed against them to be used for the purposes of the Protocol.

Annex D:* A list of products** containing controlled substances specified in Annex A

ProductsCustoms code number
1.Automobile and truck air conditioning units (whether incorporated in vehicles or not)...................
2.Domestic and commercial refrigeration and air conditioning/heat pump equipment***...................
e.g.Refrigerators...................
Freezers...................
Dehumidifiers...................
Water coolers...................
Ice machines...................
Air conditioning and heat pump units...................
3.Aerosol products, except medical aerosols...................
4.Portable fire extinguisher...................
5.Insulation boards, panels and pipe covers...................
6.Pre-polymers...................
* This Annex was adopted by the Third Meeting of the Parties in Nairobi, 21 June 1991 as required by paragraph 3 of Article 4 of the Protocol.
** Though not when transported in consignments of personal or household effects or in similar non-commercial situations normally exempted from customs attention.
*** When containing controlled substances in Annex A as a refrigerant and/or in insulating material of the product.

Annex E: Controlled substance

GroupSubstanceOzone-Depleting Potential
Group I
CH3Brmethyl bromide0.6

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