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Gases - Explosion and Flammability Concentration Limits Flame and explosion limits for gases - propane, methane, butane, acetylene and more

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The Flammable Range (Explosive Range) is the concentration range of a gas or vapor that will burn (or explode) if an ignition source is introduced.
Three basic requirements must be met for explosion to take place:
  1. flammable substance - fuel
  2. oxidizer - oxygen or air
  3. source of ignition - spark or high heat
Below the explosive or flammable range the mixture is too lean to burn and above the upper explosive or flammable limit the mixture is too rich to burn. The limits are commonly called the "Lower Explosive or Flammable Limit" (LEL/LFL) and the "Upper Explosive or Flammable Limit" (UEL/UFL).
The lower and upper explosion concentration limits for some commonly used gases are indicated in the table below. Some of the gases are commonly used as fuel in combustion processes.
Fuel Gas"Lower Explosive or Flammable Limit"
(LEL/LFL)
(% by volume of air)
"Upper Explosive or Flammable Limit"
(UEL/UFL)
(% by volume of air)
Acetaldehyde460
Acetic acid419.9
Acetone2.612.8
Acetyl chloride7.319
Acetylene2.581
Acrolein2.831
Acrylonitrile3.017
Allyl chloride2.911.1
Ammonia1528
Arsine5.178
Benzene1.356.65
1,3-Butadiene2.012
n-Butane1.868.41
iso-Butane1.808.44
iso-Butene1.89.0
Butyl acetate18
Butyl alcohol, Butanol111
Butylene1.989.65
Butyl methyl ketone18
Carbon Disulfide1.350
Carbon Monoxide1275
Cyanogen6.042.6
Cyclobutane1.811.1
Cyclohexane1.38
Cyclohexanol19
Cyclopropane2.410.4
Cyclohexanone19
Dekane0.85.4
Diborane0.888
1,1-Dichloroethane611
Diethyl Ether1.936
Diesel fuel0.67.5
Diethanolamine213
Diethylamine213
Diethylether1.948
Dimethyl sulphoxide342
Diisobutyl ketone16
Diisopropyl ether121
Epichlorohydrin421
Ethane312.4
Ethylene2.7528.6
Ethyl Alcohol, Ethanol3.319
Ethyl acetate212
Ethylamine3.514
Ethylbenzene1.07.1
Ethyl Chloride3.815.4
Etylene glycol322
Ethylene oxide3100
Fuel Oil No.10.75
Furan214
Furfural219
Gasoline1.47.6
Glycerol319
Heptane1.06.7
Hexane1.17.5
Hydrogen475
Hydrogen sulfide4.346
Isobutane1.89.6
Isobutyl alcohol211
Isophorone14
Isopropyl Alcohol, Isopropanol212
Kerosene Jet A-10.75
Methane4.416.4
Methyl Acetate316
Methyl Alcohol, Methanol6.736
Methyl Chloride10.717.4
Methyl Ethyl Ketone1.810
Mineral spirits0.76.5
Naphthalene0.95.9
n-Heptane1.06.0
n-Hexane1.257.0
n-Pentene1.657.7
Naphtalene0.95.9
Neopentane1.387.22
Neohexane1.197.58
Nitrobenzene29
Nitromethane7.322.2
n-Octane1.07
iso-Octane0.795.94
n-Pentane1.47.8
iso-Pentane1.329.16
Propane2.110.1
Propyl acetate28
Propylene2.011.1
Propylene oxide2.336
Pyridine212
Silane1.598
Styrene1.16.1
Tetrahydrofuran212
Toluene1.276.75
Trichloroethylene1390
Triptane1.086.69
Turpentine0.8
Vinyl acetate2.613.4
Vinyl chloride3.633
p-Xylene1.06.0
Note! The limits indicated are for gas and air at 20oC and atmospheric pressure.
It is important that areas that store flammable gases are well ventilated. When designing ventilation systems be aware of the specific gravity of the actual gas. The gas mixture from a leakage will not be homogeneous and lighter gases concentrates along the ceiling. Heavy gases concentrates along the floor.
Ventilation, natural or mechanical, must be sufficient to limit the concentration of flammable gases or vapors to a maximum level of 25% of their "Lower Explosive or Flammable Limit" (LEL/LFL).
  • Minimum ventilation required: 1 cfm/ft2 (20 m3/h m2)
  • Recommended ventilation: 2 cfm/ft2 (40 m3/h m2) or 12 air changes per hour - half the air supplied and exhausted near the ceiling and half the air supplied and exhausted near the floor

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