How to avoid Glycine losses in a GV dual activated solution for Carbondioxide absorption?

How to avoid Glycine losses in a GV dual activated solution for Carbondioxide absorption?
I am currently working on improving Efficiency for CO2 absorption of a process plant. Dual activated GV solution (K2CO3+Glycine+DEA) system is used for CO2 absorption. It is observerd that Glycine losses are significant inspite of its low volatility and high stability towards oxidation. What can be possible reason for Glycine loss and how can we avoid it?
- Prem Baboo· National Fertilizers Ltd.,India
  Dear Sundeep
  The CO2 removal unit containing following percentage of Glycene,the loss of Glycene can be control by maintaining temperature as per attached flow digram, higher temp lead to loss of glycene.
  K₂CO₃ -27%
  GLYCENE- 1.2%
  DEA -1.0%
  VANADIUM- 0.4%
  CHEMISTRY INVOLVED
  ABSORBTION REACTION
  K₂CO₃+H₂0+CO2 =2 KHCO₃
  REGENERATION REACTION
  2KHCO₃ +HEAT = K₂CO₃ +H₂0+CO₂
  _{Please find attached herewith link & attached diagram.}
  _{Good Luck !}
  _{Prem Baboo}
  
  Source
  Technical Report:"Latest technique adopted in Ammonia Plant to improve Energy"
  Prem Baboo
  [Show abstract]
  Full-text available · Technical Report · Dec 2015
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  Dec 16, 2015·
Sundeep Pothula· Birla Institute of Technology and Science Pilani
Thanks a lot for your reply Sir,
But can I know
1. How is Glycine escaping at higher temperatures irrespective of its High Volatility (B.Pt around 230C)?
2.Is there any effect of Aeration on DEA & Glycine?
3. Does reflux in the system (Water or Condensate) effects the absorption process? (Increasing or decreasing the CO2 Slip)?

Dec 17, 2015·
Prem Baboo· National Fertilizers Ltd.,India
Dear Sundeep
Aeration cannot be done, for passivation V₂O₅ solution is used. You are saying right but How much partial pressure of GV in multi components system?
Addition of Vanadium as Corrosion Inhibitor, Static and Dynamic Passivation (0.5 % V₂O₅)
Iron content of the solution representation equilibrium (iron content more than 200-300ppm considered excessively high).
V+5 Protecting Layer( 5-10 % of total vanadium content).
V+5 equilibrium with V⁺4 V⁵⁺ + Fe2 = V^{4+ +} Fe³⁺
Operating Parameters
Temperature - Hot aqueous solution to increase the rate of reaction. - Keep the bicarbonate in the dissolved form. - Boiling point temperature for Re generators.
Pressure - High pressure in absorber increase the solubility of process gas in GV solution.solution. Reflux is not suitable for this process generally distillation process in used or to separation process.
Amine Solution is the best option for capturing CO²as shown in attached table
Please find attached herewith tables
Regards,